I'm not clear on what type of outgassing you'll get doing Laser ablation of the powder coated surface. I'm guessing that the cheap powder I've got is either an epoxy or a polyester, but princess auto provides zero information (not even an MSDS) for it.
I'd be tempted to carefully pre-heat the metal almost to the point of melting the powder (or sit it on a hot-plate) to minimize the amount of time it takes to get your bond.
Maybe consider using something other than the powder for your mask coating that you are burning off. I had very good results burning off water-based acrylic paints or masking tape in the past... You might be able to do some very nice work by laser-cleaning mask off the metal, all the way down to the base stock, shake-n-baking the powder into the cleaned areas, then removing the mask?